A fresh CNF based microwave silicon
transistor chip. After three weeks of putting it in a woodpile, the chip
was partially degraded with the help of fungi.
Credit: Jung-Hun Seo, Shaoqin Gong and Zhenqiang Ma/University of Wisconsin-Madison
Portable electronics users tend to upgrade
their devices frequently as new technologies offering more functionality
and more convenience become available. A report published by the U.S.
Environmental Protection Agency in 2012 showed that about 152 million
mobile devices are discarded every year, of which only 10 percent is
recycled -- a legacy of waste that consumes a tremendous amount of
natural resources and produces a lot of trash made from expensive and
non-biodegradable materials like highly purified silicon.
Now researchers from the University of Wisconsin-Madison have come up
with a new solution to alleviate the environmental burden of discarded
electronics. They have demonstrated the feasibility of making microwave
biodegradable thin-film transistors from a transparent, flexible
biodegradable substrate made from inexpensive wood, called cellulose
nanofibrillated fiber (CNF). This work opens the door for green,
low-cost, portable electronic devices in future.
In a paper published this week in the Applied Physics Letters from AIP Publishing, the researchers describe the biodegradable device.
"We found that cellulose nanofibrillated fiber based transistors
exhibit superior performance as that of conventional silicon-based
transistors," said Zhenqiang Ma, the team leader and a professor of
electrical and computer engineering at the UW-Madison. "And the
bio-based transistors are so safe that you can put them in the forest,
and fungus will quickly degrade them. They become as safe as
fertilizer."
Nowadays, the majority of portable electronics are built on
non-renewable, non-biodegradable materials such as silicon wafers, which
are highly purified, expensive and rigid substrates, but cellulose
nanofibrillated fiber films have the potential to replace silicon wafers
as electronic substrates in environmental friendly, low-cost, portable
gadgets or devices of the future.
Cellulose nanofibrillated fiber is a sustainable, strong, transparent
nanomaterial made from wood. Compared to other polymers like plastics,
the wood nanomaterial is biocompatible and has relatively low thermal
expansion coefficient, which means the material won't change shape as
the temperature changes. All these superior properties make cellulose
nanofibril an outstanding candidate for making portable green
electronics.
To create high-performance devices, Ma's team employed silicon
nanomembranes as the active material in the transistor -- pieces of
ultra-thin films (thinner than a human hair) peeled from the bulk
crystal and then transferred and glued onto the cellulose nanofibrill
substrate to create a flexible, biodegradable and transparent silicon
transistor.
But to make portable electronics, the biodegradable transistor needed
to be able to operate at microwave frequencies, which is the working
range of most wireless devices. The researchers thus conducted a series
of experiments such as measuring the current-voltage characteristics to
study the device's functional performance, which finally showed the
biodegradable transistor has superior microwave-frequency operation
capabilities comparable to existing semiconductor transistors.
"Biodegradable electronics provide a new solution for environmental
problems brought by consumers' pursuit of quickly upgraded portable
devices," said Ma. "It can be anticipated that future electronic chips
and portable devices will be much greener and cheaper than that of
today."
Next, Ma and colleagues plan to develop more complicated circuit system based on the biodegradable transistors.
Story Source:
The above post is reprinted from
materials provided by
American Institute of Physics.
Note: Materials may be edited for content and length.